Publications

Prior to UCD

12) M.K. Sharma, H.M. Weinert, B. Li, C. Wölper, J.T. Henthorn, G.E. Cutsail III, G. Haberhauer, and S. Schulz, Syntheses and Structures of 5-Membered Heterocycles Featuring 1,2-Diphospha-1,3-Butadiene and Its Radical
Anion, Angewandte Chemie International Edition, 2023, 62, e202309466, DOI:10.1002/anie.202309466

11) J.T. Henthorn, G.E. Cutsail III, T. Weyhermüller, and S. DeBeer, Stabilization of Intermediate Spin States in Mixed-valent Diiron Dichalcogenide Complexes, Nature Chemistry, 2022, 14, 328-333, DOI:10.1038/s41557-021-00853-5

10) J.T. Henthorn and S. DeBeer, Selenium Valence-to-core X-ray Emission Spectroscopy and Kβ HERFD X-ray Absorption Spectroscopy as Complementary Probes of Chemical and Electronic Structure, Inorganic Chemistry, 2022, 61(6), 2760-2767, DOI: 10.1021/acs.inorgchem.1c02802

9) R.G. Castillo, A.W. Hahn, B.E. Van Kuiken, J.T. Henthorn, and S. DeBeer, Probing Physical Oxidation State by Resonant X‐ray Emission Spectroscopy: Applications to Iron Model Complexes and Nitrogenase, Angewandte Chemie International Edition, 2021, 60(18), 10112-10121, DOI: 10.1002/ange.202015669

8) R.G. Castillo, J.T. Henthorn, J. McGale, D. Manganas, and S. DeBeer, Kβ X‐Ray Emission Spectroscopic Study of a Second‐Row Transition Metal (Mo) and Its Application to Nitrogenase‐Related Model Complexes, Angewandte Chemie International Edition, 2020, 59(31), 12965-12975, DOI: 10.1002/anie.202003621

7) C. Van Stappen, L. Decamps, G.E. Cutsail III, R. Bjornsson, J.T. Henthorn, J. Birrell, S. DeBeer, The Spectroscopy of Nitrogenases, Chemical Reviews, 2020, 120(12), 5005-5081, DOI: 10.1021/acs.chemrev.9b00650

6) J.T. Henthorn, R.J. Arias, S. Koroidov, T. Kroll, D. Sokaras, U. Bergmann, D.C. Rees, and S. DeBeer, Localized Electronic Structure of Nitrogenase FeMoco Revealed by Selenium K-Edge High Resolution X-ray Absorption
Spectroscopy, Journal of the American Chemical Society, 2019, 141(34), 13676–13688, DOI: 10.1021/jacs.9b06988

5) J.K. Kowalska, J.T. Henthorn, C. Van Stappen, C. Trncik, O. Einsle, D. Keavney, S. DeBeer, X-ray Magnetic Circular Dichroism Spectroscopy Applied to Nitrogenase and Related Models: Experimental Evidence for a Spin-Coupled Molybdenum(III) Center, Angewandte Chemie International Edition, 2019, 58(28), 9373–9377, DOI: 10.1002/anie.201901899

4) J.T. Henthorn and T. Agapie, Modulation of Proton-Coupled Electron Transfer through Molybdenum-quinonoid
Interactions, Inorgic Chemistry, 2016, 55(11), 5337–5342, DOI: 10.1021/acs.inorgchem.6b00331

3) J.T. Henthorn, S. Lin, and T. Agapie, Combination of Redox Active Ligand and Lewis Acid for Dioxygen Reduction with π-Bound Molybdenum Quinonoid Complexes, Journal of the American Chemical Society, 2015, 137(4), 1458–1464, DOI: 10.1021/ja5100405

2) J.T. Henthorn and T. Agapie, Dioxygen Reactivity with Ferrocene-Lewis Acid Pairing: Reduction to a Boron Peroxide in the Presence of Tris(pentafluorophenyl)borane, Angewandte Chemie International Edition, 2014, 53(47), 12893–12896, DOI: 10.1002/anie.201408462

1) A.A. Reinard, J. Henthorn, R. Komm, and F. Hill, Evidence that Temporal Changes in Solar Subsurface Helicity Precede Active Region Flairing., Astrophysical Journal Letters, 2010, 710, L121–L125, DOI: 10.1088/2041-8205/710/2/L121